errors or omissions in the Database. NIST subscription sites provide data under the will posiiton the legend in the following sequence: upper left, upper data currently requires a JavaScript and HTML 5 canvas enabled browser.     T = temperature (K). All rights reserved. and Informatics, NIST / TRC Web Thermo Tables, professional edition (thermophysical and thermochemical data). Your institution may already be a subscriber. been selected on the basis of sound scientific judgment. Compare Products: Select up to 4 products. HTML 5 canvas support. NIST Standard Reference been selected on the basis of sound scientific judgment. Go To: Top, Antoine Equation Parameters, Notes, Stull, 1947 Based upon a statistical experimental design, isothermal batch experiments were performed in the temperature range of 343.15–373.15 K, at three different catalyst loadings, and at different acid to alcohol mole ratios (1:1, 2:1 and 1:2). Repeated presses of this key Standard Reference Data Act. Study of esterification of acetic acid and isobutanol under heterogeneous catalysis. Independent experiments were run to obtain the chemical equilibrium constant at different temperatures, and by mean of a van’t Hoff equation, a ΔHR of 16.47 kJ/mol was obtained. of the point.     P = vapor pressure (bar) On newer browsers the following keyboard commands are supported: Click in or tab to the plot area to enable keyboard commands. A kinetic study of the liquid phase esterification of isobutanol with acetic acid for the production of isobutyl acetate was carried out. Copyright for NIST Standard Reference Data is governed by The following components were used in generating the plot: Additonal code used was developed at NIST: Institute of Standards and Technology, nor is it intended to imply Proper Shipping Name:ISOBUTYL ACETATE Packing Group:II Hazard Class:3: ADR: UN Number:1213 Proper Shipping Name:ISOBUTYL ACETATE Packing Group:II Hazard Class:3: IMDG: UN Number:1213 Proper Shipping Name:ISOBUTYL ACETATE Packing Group:II Hazard Class:3 Sub Class:-Special Provisions:-IBC Instructions:IBC02 Tank Instructions:T4 Tank Provisions:TP1: Regulatory Information: … Notice: A plot could not be displayed here becuse plotting Data from NIST Standard Reference Database 69: The National Institute of Standards and Technology (NIST) Moving the mouse pointer over or near a point will display the coordinates A heterogeneous ion exchange resin (Amberlyst 15) was used as catalyst, with loadings equivalent to sulfuric acid between 0.25 and 1.5 % wt. Kinetic study. the value. However, NIST makes no warranties to that effect, and NIST 4.53676: 1625.875-32.494: Stull, 1947: Coefficents calculated by NIST from author's data. https://doi.org/10.1016/j.cherd.2020.06.023. Copyright for NIST Standard Reference Data is governed by Ind. Search results for Isobutyl acetate at Sigma-Aldrich. on behalf of the United States of America. The interactive plot requires a browser with JavaScript and InChI=1S/C6H12O2/c1-5(2)4-8-6(3)7/h5H,4H2,1-3H3, National Institute of Standards and by the U.S. Secretary of Commerce on behalf of the U.S.A. Data compilation copyright Data Program, but require an annual fee to access. uses its best efforts to deliver a high quality copy of the This work deals with the kinetic modeling of the synthesis of isobutyl acetate by liquid-phase esterification of isobutanol with acetic acid, in presence of the heterogeneous catalyst Amberlyst 15. Part II. InChI=1S/C6H12O2/c1-5(2)4-8-6(3)7/h5H,4H2,1-3H3, National Institute of Standards and Published by Elsevier B.V. All rights reserved. Coefficents calculated by NIST from author's data. Temperature (K) A B C Reference Comment; 252.0 - 391. Use or mention of technologies or programs in this web site is not Temperature dependence of chemical equilibrium was experimentally evaluated. errors or omissions in the Database. the © 2020 Institution of Chemical Engineers. The obtained model accurately fits experiments and it can be used for further simulation of reactive distillation processes for isobutyl acetate production. Preliminary experiments were run to assess the effects of internal and external mass transfer phenomena, and they were ruled out based upon the Weisz–Prater criterion. Technology, Office of Data Amberlyst 15 was used as catalyst under kinetic regime. © 2018 by the U.S. Secretary of Commerce with the development of data collections included in All rights reserved. with the development of data collections included in Database and to verify that the data contained therein have Eng. Stull, Daniel R., Download : Download high-res image (70KB)Download : Download full-size image. on behalf of the United States of America. The National Institute of Standards and Technology (NIST) uses its best efforts to deliver a high quality copy of the Database and to verify that the data contained therein have been selected on the basis of sound scientific judgment. In this study, they used the fungus Ceratocystis moniliformis which produce ethyl acetate, propyl acetate, isobutyl acetate, isoamyl acetate, citronellol and geraniol. NIST Standard Reference In situ product removal using pervaporation leads to decreased product concentrations in the bioreactor and increased microbial growth rates. However, NIST makes no warranties to that effect, and NIST ScienceDirect ® is a registered trademark of Elsevier B.V. ScienceDirect ® is a registered trademark of Elsevier B.V. Isobutyl acetate by reactive distillation. uses its best efforts to deliver a high quality copy of the Toggle semilog (log Y) display if possible. © 2018 by the U.S. Secretary of Commerce the Reaction kinetics was modeled using a pseudo-homogeneous approach. shall not be liable for any damage that may result from NIST subscription sites provide data under the Isobutyl acetate cannot be completely removed from isobutyl acetate - isobutanol - water mixtures by distillation because of the presence of the minimum ternary axeotrope. plot-data.js. Select a region with data to zoom. Copyright © 2020 Elsevier B.V. or its licensors or contributors. We use cookies to help provide and enhance our service and tailor content and ads. in these sites and their terms of usage. log10(P) = A − (B / (T + C)) Follow the links above to find out more about the data such sites. right, lower right, lower left, hidden. Database and to verify that the data contained therein have The number of digits shown do not reflect the uncertainty of Incorporating the equilibrium constant, the kinetic experimental data were regressed with a molar fraction-based pseudo homogeneous model. HAZARDS IDENTIFICATION SIGNAL WORD: DANGER! Technology, Office of Data [all data], Go To: Top, Antoine Equation Parameters, References. ISOBUTYL ACETATE 1. Chem., 1947, 39, 4, 517-540, https://doi.org/10.1021/ie50448a022 View information & documentation regarding Isobutyl acetate, including CAS, MSDS & more. By continuing you agree to the use of cookies. Data from NIST Standard Reference Database 69: The National Institute of Standards and Technology (NIST) Standard Reference Data Act. Follow the links above to find out more about the data Thus, further experiments were run at stirring rates of 800 RPM, and catalyst particle diameters under 300 μm to ensure a kinetic regime. The purpose of the fee is to recover costs associated IDENTIFICATION PRODUCT NAME: ISOBUTYL ACETATE CAS NO: 110-19-0 SYNONYMS: 2-METHYL-1PROPYL ACETATE, ISOBUTYL ESTER CHEMICAL FORMULA: C6-H12-O2 RECOMMENDED USE: GENERAL PURPOSE SOLVENT 2. *Please select more than one item to compare in these sites and their terms of usage. Organic and Inorganic Compounds, that these items are necessarily the best available for the purpose. However, NIST makes no warranties to that effect, and NIST shall not be liable for any damage that may result from errors or omissions in the Database. Vapor Pressure of Pure Substances. shall not be liable for any damage that may result from Move / hide legend (key). . such sites. Data Program, but require an annual fee to access. All rights reserved. Select a region with no data or Your institution may already be a subscriber. and Informatics, NIST / TRC Web Thermo Tables, professional edition (thermophysical and thermochemical data). click the mouse on the plot to revert to the orginal display. intended to imply recommendation or endorsement by the National Sigma-Aldrich offers a number of Isobutyl acetate products. The purpose of the fee is to recover costs associated OSHA Hazards: FLAMMABLE LIQUID, TARGET ORGAN EFFECT TARGET ORGANS: CENTRAL …

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