Francis L. C. Morgan, Lorenzo Moroni, Matthew B. Baker. Gelatin-Based Hydrogels through Homobifunctional Triazolinediones Targeting Tyrosine Residues. )–H activation with DNA-encoding. Imine bonding self-repair hydrogels after periodate-triggered breakage of their cross-links. BF Noncovalent and Dynamic Covalent Chemistry Strategies for Driving Thermoresponsive Phase Transition with Multistimuli and Controlled Encapsulation/Release. NIH Expanding the Versatility of Microbial Transglutaminase Using α‐Effect Nucleophiles as Noncanonical Substrates. This site needs JavaScript to work properly. Yan Zhang, Yunchuan Qi, Sébastien Ulrich, Mihail Barboiu, Olof Ramström. Oxime conjugation in protein chemistry: from carbonyl incorporation to nucleophilic catalysis. Synthesis, characterization, superoxide anion scavenging evaluation, skin sensitization predictions, and DFT calculations for a new isonicotinylhydrazide analog. Stéphane Duflocq, Jingjing Zhou, Florent Huguenot, Michel Vidal, Wang-Qing Liu. Nasreddine Kanfar, Ahmad Mehdi, Pascal Dumy, Sébastien Ulrich, Jean-Yves Winum. Secondary Amino Alcohols: Traceless Cleavable Linkers for Use in Affinity Capture and Release. Yujia Xia, Jinhui Cai, Huawen Huang, Guo-Jun Deng. Anastasia I. Solomatina, Pavel S. Chelushkin, Tatiana O. Abakumova, Vladimir A. Zhemkov, Meewhi Kim, Ilya Bezprozvanny, Vladislav V. Gurzhiy, Alexey S. Melnikov, Yuri A. Anufrikov, Igor O. Koshevoy, Shih-Hao Su, Pi-Tai Chou. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy. Protein-Directed Dynamic Combinatorial Chemistry: An Efficient Strategy in Drug Design. Nano/Microparticles Encapsulation Via Covalent Drug Conjugation. Tatyana V. Abramova, Ludmila S. Koroleva, Vladimir N. Silnikov. Learn about all the sciences, from physics, chemistry and biology, to cosmology and astronomy, across hundreds of videos, articles and practice questions. Troels Authors contributing to RSC publications (journal articles, books or book chapters) Bioconjugation with Aminoalkylhydrazine for Efficient Mass Spectrometry-Based Detection of Small Carbonyl Compounds. Haoqing Chen, Lihua Yao, Christina Brown, Carmelo J. Rizzo. oximes or hydrazine to form hydrazones. Sal and Jay cover topics covered in college organic chemistry Efficient Pictet-Spengler Bioconjugation with Developing bioorthogonal probes to span a spectrum of reactivities. Zhoulong Fan, Shuai Zhao, Tao Liu, Peng-Xiang Shen, Zi-Ning Cui, Zhe Zhuang, Qian Shao, Jason S. Chen, Anokha S. Ratnayake, Mark E. Flanagan, Dominik K. Kölmel, David W. Piotrowski, Paul Richardson, Jin-Quan Yu. Information about how to use the RightsLink permission system can be found at This metal-free cyclization provides direct access to isoxazoles and dihydropyrazoles in good to excellent yields at room temperature. This imine-forming reaction is applied in fields as diverse as polymer chemistry, biomaterials and hydrogels, dynamic combinatorial chemistry, organic synthesis, and chemical biology. The formation of oximes and hydrazones is employed in numerous scientific fields as a simple and versatile conjugation strategy. Periodate-Mediated Oxidative Cleavage of 3′-Ribonucleotide…, Scheme 3. Among the most effective new strategies has been the development of substituents near the reactive aldehyde group that either transfer protons at the transition state or trap the initially formed tetrahedral intermediates. Biomolecular dynamic covalent polymers for DNA complexation and siRNA delivery. Tunable Interpenetrating Polymer Network Hydrogels Based on Dynamic Covalent Bonds and Metal–Ligand Bonds. generated ylides. Periodate-Mediated Oxidative Cleavage of Vicinal Diols 6 or 1,2-Amino Alcohols 7, Scheme 3. Site-specific bioconjugation and self-assembly technologies for multi-functional biologics: on the road to the clinic. 2019 Nov 8;11(1):224-231. doi: 10.1039/c9sc04821a. 2018 Sep;10(9):946-952. doi: 10.1038/s41557-018-0082-z. Frontiers in Bioengineering and Biotechnology. Colloids and Surfaces A: Physicochemical and Engineering Aspects. Therefore, oximes can be used for the identification of ketone or aldehyde. Synthesis, X-ray crystal structure, DFT calculations, spectroscopic characterization and redox behaviour of a rhodium(III) complex of an anthracene–pyridylhydrazone ligand. The basic chemical properties of reactants and products in this reaction are then reviewed, with an eye to understanding the reaction’s mechanism and how reactant structure controls rates and equilibria in the process. Site-Selective Protein Modification: From Functionalized Proteins to Functional Biomaterials. Ingrid Vikøren Mo, Yiming Feng, Marianne Øksnes Dalheim, Amalie Solberg, Finn L. Aachmann, Christophe Schatz, Bjørn E. Christensen. Basic understanding of basic high school or college chemistry assumed (although there is some review). These metrics are regularly updated to reflect usage leading up to the last few days. Jessica Wahsner, Pauline Désogère, Eric Abston, Katherine A. Graham-O’Regan, Junfeng Wang, Nicholas J. Rotile, Markus D. Schirmer, Diêgo Dos Santos Ferreira, Jingyi Sui, Bryan C. Fuchs, Michael Lanuti. D. L. Obydennov, L. R. Khammatova, O. S. Eltsov, V. Y. Sosnovskikh. Epub 2016 Mar 23. Preparation of bivalent agonists for targeting the mu opioid and cannabinoid receptors. Here, we report that simple, commercially available anthranilic acids and aminobenzoic acids act as superior catalysts for hydrazone and oxime formation, … course. Direct conversion of phenols into primary anilines with hydrazine catalyzed by palladium. Synthesis, Solvatochromic Performance, pH Sensing, Dyeing Ability, and Antimicrobial Activity of Novel Hydrazone Dyestuffs. Indoline Catalyzed Acylhydrazone/Oxime Condensation under Neutral Aqueous Conditions. Development of a microcolumn one-site immunometric assay for a protein biomarker: Analysis of alpha1-acid glycoprotein. This imine-forming reaction is applied in fields as diverse as polymer chemistry, biomaterials and hydrogels, dynamic combinatorial chemistry, organic synthesis, and chemical biology. Information about reproducing material from RSC articles with different licences White, Haewon Song, Sara Da Ros, Roger Schibli, Jeffrey W. Bode, Simon M. Ametamey. -Substituted Pyrrolyl Alanine Derivatives. Synthesis of polysubstituted pyridines from oxime acetates using NH Aline Chevalier, Artem Osypenko, Jean-Marie Lehn, Daniel Meyer. Complex-decorated surfactant-encapsulated clusters (CD-SECs) as novel multidynamic hybrid materials. … Selective modification of a native protein in a patient tissue homogenate using palladium nanoparticles. If you are not the author of this article and you wish to reproduce material from Rapid and reversible hydrazone bioconjugation in cells without the use of extraneous catalysts. Find more information on the Altmetric Attention Score and how the score is calculated. Selective Oxidation of N-Terminal Amines 34 with Oxone, Scheme 8. Comparison between the kinetic stabilities in a series of isostructural conjugates, Comparison of hydrolytic stability between, Comparison of reaction conditions and second-order rate constants of several bioconjugation reactions. Marie-Luise Frey, Johanna Simon, Maximilian Brückner, Volker Mailänder, Svenja Morsbach, Katharina Landfester.

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